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个人信息Personal Information
教授
博士生导师
硕士生导师
任职 : 现任大连理工大学化工学院教授、博士生导师。同时担任“膜科学与技术”期刊编委，膜学会理事（筹），膜工业协会工程与应用专业委员会及特种分离膜专业委员会委员、中国兵工学会活性炭测试分析与应用研究分会委员等。
性别：男
毕业院校：大连工学院
学位：硕士
所在单位：化工学院
学科：化学工艺. 膜科学与技术. 功能材料化学与化工
办公地点：化工综合楼A201
联系方式：微信/电话 13500711370
电子邮箱：wangth@dlut.edu.cn
Structure and gas permeation of nanoporous carbon membranes based on RF resin/F-127 with variable catalysts
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论文类型：期刊论文
发表时间：2014-12-14
发表刊物：JOURNAL OF MATERIALS RESEARCH
收录刊物：SCIE、EI
卷号：29
期号：23
页面范围：2881-2890
ISSN号：0884-2914
摘要：Nanoporous carbon membranes (NCMs) were fabricated by the blends of resorcinol-formaldehyde (RF) resin and Pluronic F-127 through the processes of assembly, membrane-casting, solidification, and pyrolysis. The effect of the catalyst type (i.e., NaOH and Na2CO3) on the structure and property of precursors and their derived NCMs was investigated. The as-obtained precursors and NCMs were characterized by thermogravimetry, differential scanning calorimetry, x-ray diffraction, Fourier transform infrared spectroscopy, transmission electron microscopy, elemental analysis, nitrogen adsorption, and gas permeation techniques. The results have shown that defect-free NCMs can be easily procured by the NaOH and Na2CO3 catalysts. In contrast, the precursor made from the Na2CO3 catalyst exhibits higher char yield than that from NaOH after pyrolysis. NaOH-based NCMs are beneficial for the separation of H-2/N-2 and CO2/N-2 gas pairs. Na2CO3-based NCMs are more favorable for the separation of O-2/N-2 with an ideal selectivity of 6.29 and an O-2 permeability of 3.27 Barrer.