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个人信息Personal Information
教授
博士生导师
硕士生导师
任职 : 现任大连理工大学化工学院教授、博士生导师。同时担任“膜科学与技术”期刊编委，膜学会理事（筹），膜工业协会工程与应用专业委员会及特种分离膜专业委员会委员、中国兵工学会活性炭测试分析与应用研究分会委员等。
性别：男
毕业院校：大连工学院
学位：硕士
所在单位：化工学院
学科：化学工艺. 膜科学与技术. 功能材料化学与化工
办公地点：化工综合楼A201
联系方式：微信/电话 13500711370
电子邮箱：wangth@dlut.edu.cn
Microporous Carbon Membranes from Sulfonated Poly(phthalazinone ether sulfone ketone): Preparation, Characterization, and Gas Permeation
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论文类型：期刊论文
发表时间：2011-10-15
发表刊物：JOURNAL OF APPLIED POLYMER SCIENCE
收录刊物：Scopus、SCIE、EI
卷号：122
期号：2
页面范围：1190-1197
ISSN号：0021-8995
关键字：microstructure; pyrolysis; membranes; gas permeation
摘要：Microporous carbon membranes (MCM) were prepared from sulfonated poly(phthalazinone ether sulfone ketone) (SPPESK) through stabilization and pyrolysis processes. The effects of sulfonation degree (SD) of SPPESK and the stabilization temperature on the structure and gas permeation of MCM were investigated. The thermal decomposition behavior of SPPESK was studied by thermogravimetric analysis-mass spectrometry. The evolution of functional groups on membrane surface was detected by Fourier transform infrared spectroscopy during heat treatment. The resultant MCM was characterized by X-ray diffraction, Raman spectroscopy, nitrogen adsorption technique and pure gas permeation test (including the gases of H(2), CO(2), O(2), and N(2)), respectively. The results have shown that the removal of sulfonic acid groups in SPPESK leads to a weight loss stage in the temperature range of 250-450 degrees C. The surface area, maximum pore volume, and gas permeability of MCM increase with the SD increasing from 59 to 75%, together with the reduction of selectivity. Similarly, the gas permeability of MCM also increases with elevating the stabilization temperature from 350 to 400 degrees C at the loss of selectivity. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 122: 1190-1197, 2011