王同华

个人信息Personal Information

教授

博士生导师

硕士生导师

任职 : 现任大连理工大学化工学院教授、博士生导师。同时担任“膜科学与技术”期刊编委,膜学会理事(筹),膜工业协会工程与应用专业委员会及特种分离膜专业委员会委员、中国兵工学会活性炭测试分析与应用研究分会委员等。

性别:男

毕业院校:大连工学院

学位:硕士

所在单位:化工学院

学科:化学工艺. 膜科学与技术. 功能材料化学与化工

办公地点:化工综合楼A201

联系方式:微信/电话 13500711370

电子邮箱:wangth@dlut.edu.cn

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Low-cost dye-sensitized solar cell based on nine kinds of carbon counter electrodes

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论文类型:期刊论文

发表时间:2011-06-01

发表刊物:ENERGY & ENVIRONMENTAL SCIENCE

收录刊物:Scopus、SCIE、EI、ESI高被引论文

卷号:4

期号:6

页面范围:2308-2315

ISSN号:1754-5692

摘要:Nine kinds of carbon materials were introduced into dye-sensitized solar cells (DSCs) system as counter electrodes (CEs). We also compared the electrochemical catalytic activity of these carbon materials with Pt for the reduction of triiodide to iodide by measuring cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and Tafel-polarization curve. The nine kinds of carbon materials in this work included synthesized well-ordered mesoporous carbon (Com), activated carbon (Ca), carbon black (Cb), conductive carbon (Cc), carbon dye (Cd), carbon fiber (Cf), carbon nanotube (Cn), discarded toner of a printer (Cp) and fullerene (C-60). All carbon materials showed electrochemical catalytic activity for triiodide reduction in the DSCs system. In particular, the synthesized Com showed excellent electrochemical catalytic activity which can be comparable to the performance of Pt. After optimizing the proportion of TiO2 added into the carbon paste and the spray time of the carbon paste, the DSCs based on these carbon CEs achieved energy conversion efficiencies of 2.8-7.5%. The results demonstrate that carbon material is a promising substitute for the expensive Pt CE for low-cost DSCs.