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聚甲醛/共聚酰胺共混物的非等温结晶动力学研究

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Date of Publication:2022-10-06

Journal:中国塑料

Affiliation of Author(s):化工学院

Volume:21

Issue:7

Page Number:15-19

ISSN No.:1001-9278

Abstract:The non-isothermal crystallization kinetics of polyoxymethylene (POM)
   and polyoxymethylene/co-polyamide (POM/COPA) at different cooling rates
   were investigated uisng differential scanning calorimetry (DSC). The
   parameters of non-isothermal crystallization kinetics were obtained
   through Jeziorny, Ozawa, and MO methods. It showed that the increase of
   cooling rates made the crystallization peaks of POM and POM/COPA moved
   towards lower temperature and became wider. The addition of COPA
   increased the crystallization temperature and accelerated the
   crystallization rate. COPA played a role as a nucleating agent for
   non-isothermal crystallization of POM. Both Jeziorny and MO methods
   described this system very well.

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