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论文类型：期刊论文

发表时间：2008-07-01

发表刊物：BIOCHEMICAL ENGINEERING JOURNAL

收录刊物：SCIE、EI

卷号：40

期号：3

页面范围：537-541

ISSN号：1369-703X

关键字：biodiesel; combined bioprocess; glycerol; membrane; 1,3-propanediol

摘要：A novel integrated bioprocess combining biodiesel production by lipase with microbial production of 1,3-propanediol (1,3-PD) by Klebsiella pneumoniae using a hollow fiber membrane was investigated. Glycerol, a byproduct produced during the transesterification, can pass through the membrane and is converted to 1,3-PD directly by X pneumoniae. The highest conversion of biodiesel obtained after 20 h was 84%, and the molar yield and productivity of 1,3-PD were 0.47 mol mol(-1) and 1.7 g l(-1) h(-1), respectively. Although partial methanol (11% of the total methanol) penetrated into fermentation broth with glycerol, its effects on cell growth and products formation were not significant. The combined bioprocess avoids glycerol inhibition on lipase, reduces the production cost and raises productivity for biodiesel and 1,3-PD. (c) 2008 Elsevier B.V. All rights reserved.