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个人信息Personal Information
副教授
硕士生导师
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
电子邮箱：gaoxq@dlut.edu.cn
In situ Formation of NOx and Br Anion for Aerobic Oxidation of Benzylic Alcohols without Transition Metal
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论文类型：期刊论文
发表时间：2010-02-01
发表刊物：SYNLETT
收录刊物：SCIE
期号：3
页面范围：437-440
ISSN号：0936-5214
关键字：oxidation; alcohols; catalyst; bromate; hydroxylammonium; 2,2,6,6-tetramethylpiperidine-N-oxide
摘要：The reaction of KBrO3 and NH2OH center dot HCl in situ generates NOx and Br anion, which combine with 2,2,6,6-tetramethylpiperidine-N-oxide (TEMPO) to construct a NO-activating dioxygen, Br-assisted, TEMPO-catalyzed aerobic oxidation of alcohols. Catalyzed by KBrO/NH2OH center dot HCl/TEMPO, various benzylic alcohols can be oxidized quantitatively to their corresponding carbonyl compounds under mild conditions. The easy handling and simple product separation make the process an attractive candidate for the oxidation of alcohols.