王秀娜
个人信息Personal Information
高级工程师
性别:女
毕业院校:大连理工大学
学位:学士
所在单位:化工学院
电子邮箱:xiuna@dlut.edu.cn
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A Ligand-Free Copper-Catalyzed Decarboxylative Trifluoromethylation of Aryliodides with Sodium Trifluoroacetate Using Ag2O as a Promoter
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论文类型:期刊论文
发表时间:2011-07-01
发表刊物:SYNLETT
收录刊物:SCIE
期号:12
页面范围:1713-1716
ISSN号:0936-5214
关键字:copper-catalyzed; trifluoromethylation; decarboxylative; silver oxide; cross-coupling
摘要:A practical and ligand-free Cu-catalyzed decarboxylative trifluoromethylation of aryl iodides with sodium trifluoroacetate using Ag2O as a promoter was reported. A variety of trifluoromethyl-substituted aromatics are synthesized in moderate to excellent yields and with wide functional-group tolerance under relatively mild reaction conditions.