王秀娜

个人信息Personal Information

高级工程师

性别:女

毕业院校:大连理工大学

学位:学士

所在单位:化工学院

电子邮箱:xiuna@dlut.edu.cn

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A Ligand-Free Copper-Catalyzed Decarboxylative Trifluoromethylation of Aryliodides with Sodium Trifluoroacetate Using Ag2O as a Promoter

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论文类型:期刊论文

发表时间:2011-07-01

发表刊物:SYNLETT

收录刊物:SCIE

期号:12

页面范围:1713-1716

ISSN号:0936-5214

关键字:copper-catalyzed; trifluoromethylation; decarboxylative; silver oxide; cross-coupling

摘要:A practical and ligand-free Cu-catalyzed decarboxylative trifluoromethylation of aryl iodides with sodium trifluoroacetate using Ag2O as a promoter was reported. A variety of trifluoromethyl-substituted aromatics are synthesized in moderate to excellent yields and with wide functional-group tolerance under relatively mild reaction conditions.