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The synthesis of nitrogen-doped mesoporous carbon spheres for hydrogen storage

Release Time:2019-03-11  Hits:

Indexed by: Conference Paper

Date of Publication: 2015-10-30

Included Journals: Scopus、EI

Volume: 852

Page Number: 864-869

Abstract: The nitrogen-doped mesoporous carbon spheres have been synthesized via soft-template and hydrothermal synthetic strategies using phenol/formaldehyde resins as carbon sources and melamine as a nitrogen source. The obtained carbon spheres exhibit a spherical morphology with a size range of 3-5   m, which possess the narrow microporosity (ca. 1.2 nm) and mesoporosity (ca. 4 nm), large surface area (560-1200 m2 g-1) and high nitrogen contents (up to 15.7 wt%). Due to the well-developed porous structure and high nitrogen content, the carbon spheres show high performance for hydrogen storage, and the hydrogen adsorption capacities are in the range of 140-185 cm3 g-1, which is better than that of most activated carbons. The incorporation of nitrogen into carbons is favored for hydrogen uptake in low pressure. ? 2016 Trans Tech Publications, Switzerland.

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