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[mu-2-(9-Anthrylmethyl)-2-azapropane1,3-dithiolato-kappa S-4 : S ']bis[tricarbonyl-iron(I)]

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Indexed by:期刊论文

Date of Publication:2007-07-01

Journal:ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Included Journals:SCIE、Scopus

Volume:63

Issue:7

Page Number:M1997-U1881

ISSN No.:1600-5368

Abstract:The title compound, [ Fe-2( C17H15NS2)( CO)(6)], has been prepared as an azadithiolatoiron model for the active site of iron-only hydrogenase. Each Fe atom is coordinated by two S atoms and three carbonyl groups in a distorted square-pyramidal geometry and the Fe-Fe bond length [ 2.5040 ( 8) angstrom] agrees with values found in other model structures.

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