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Heptamethine cyanine dyes with a large stokes shift and strong fluorescence: A paradigm for excited-state intramolecular charge transfer

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Indexed by: Journal Article

Date of Publication: 2005-03-30

Journal: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Included Journals: PubMed、SCIE、Scopus

Volume: 127

Issue: 12

Page Number: 4170-4171

ISSN: 0002-7863

Abstract: New heptamethine cyanine dyes with an alkylamino group at the central position were found to exhibit a large Stokes shift (>140 nm) and strong fluorescence. They were suggested to be a new paradigm for excited-state intramolecular charge transfer (ICT). The configuration change of the bridgehead amine accompanying ICT was investigated in different viscosity and pH media.

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