Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2013-12-02

Journal: TETRAHEDRON

Included Journals: Scopus、SCIE

Volume: 69

Issue: 48

Page Number: 10262-10266

ISSN: 0040-4020

Key Words: Copper-mediated; Oxidation; Trifluoromethylthiolation; Sodium trifluoroacetate; Synthetic methods

Abstract: A practical three-component copper-mediated oxidative trifluoromethylthiolation of aryl boronic acids with cheap and readily available sodium trifluoroacetate and elemental sulfur is reported. A variety of trifluoromethylthio-substituted aromatics are synthesized in moderate yields under mild reaction conditions. (C) 2013 Elsevier Ltd. All rights reserved.