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论文类型：期刊论文

发表时间：2014-01-01

发表刊物：PLASMA CHEMISTRY AND PLASMA PROCESSING

收录刊物：SCIE、EI

卷号：34

期号：1

页面范围：217-228

ISSN号：0272-4324

关键字：Surface discharge plasma reactor; Active species; Elemental mercury; Mercury oxidation

摘要：A surface dielectric barrier discharge plasma reactor was employed to study Hg-0 oxidation in coal-fired flue gas. The experimental results showed that 98 % of Hg-0 oxidation efficiency and 13.7 mu g kJ(-1) of energy yield were obtained under a specific energy density (SED) of 7.9 J L-1. Increasing SED was beneficial for Hg-0 oxidation due to higher production of active species. Higher initial concentration resulted in lower Hg-0 oxidation efficiency, but higher amount of Hg-0 oxidation. Water vapor inhibited Hg-0 oxidation because the generation of O-3 was suppressed. The presence of NO remarkably restrained Hg-0 oxidation, while SO2 showed little effect on Hg-0 oxidation. Roles of active species in Hg-0 oxidation were examined under different gas atmospheres (O-2 and air), indicating that O-3 played an important role in Hg-0 oxidation. Deposits on the internal surface of the reactor were analyzed by energy dispersive spectroscopy and the product was identified as HgO.