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个人信息Personal Information
教授
博士生导师
硕士生导师
任职 : fellow of chinese chemistry society,fellow of chinese chemical engineering society
性别:女
毕业院校:大连理工大学
学位:博士
所在单位:化工学院
学科:高分子材料. 高分子化学与物理. 膜科学与技术
联系方式:0411-84986095(O) Email: zhuxl@dlut.edu.cn
电子邮箱:zhuxl@dlut.edu.cn
Studies on synthesis and property of novel acid-base proton exchange membranes
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论文类型:期刊论文
发表时间:2007-05-01
发表刊物:CHINESE CHEMICAL LETTERS
收录刊物:ISTIC、SCIE
卷号:18
期号:5
页面范围:609-612
ISSN号:1001-8417
关键字:acid-base composite membrane; PEM; stability; sulfonation
摘要:Sulfonated poly(phthalazinone)s (SPPENK, SPPESK and SPPBEK) were prepared by direct polymerization reaction from sulfonated monomers. The novel acid-base membranes were composed of sulfonated polymers as the acidic compounds, and polyetherimide (PEI) as the basic compounds, casting from their N-methylpyrrolidone (NMP) solution directly onto clean glass plates at 60 C aiming at enhancing membrane toughness and other relative properties. The resulted acid-base composite membranes had excellent resistance to swelling, thermo-stability, hydrolysis resistance and oxidative resistance properties with highly ion-exchange capacity (IEC). (c) 2007 Xi Gao Jian. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.