朱秀玲

个人信息Personal Information

教授

博士生导师

硕士生导师

任职 : fellow of chinese chemistry society,fellow of chinese chemical engineering society

性别:女

毕业院校:大连理工大学

学位:博士

所在单位:化工学院

学科:高分子材料. 高分子化学与物理. 膜科学与技术

联系方式:0411-84986095(O) Email: zhuxl@dlut.edu.cn

电子邮箱:zhuxl@dlut.edu.cn

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Soluble aromatic poly(ether amide)s containing aryl-, alkyl-, and chloro-substituted phthalazinone segments

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论文类型:期刊论文

发表时间:2004-04-15

发表刊物:JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

收录刊物:Scopus、SCIE、EI

卷号:42

期号:8

页面范围:2026-2030

ISSN号:0887-624X

关键字:polycondensation; high performance; synthesis

摘要:A series of novel aromatic diamines (2-4) containing the alkyl-, aryl, or chloro-substituted group of phthalazinone segments were synthesized via two synthetic steps starting from 4-(3-R-4-hydroxyphenyl)-2,3-phthalazinone-1 (R = Ph, CH3, Cl). Three series of aromatic polyamides containing phthalazinone moieties were prepared through diamines 2-4 reacting with different aromatic dicarboxylic acids via a direct Yamazaki-Higashi phosphorylation polycondensation reaction. The resulting aromatic polyamides had inherent viscosities in the range of 0.40-0.76 dL/g. The thermal property of the polyamides was examined with DSC and thermogravimetric analysis. The glass-transition temperatures of these polyamides ranged from 298 to 340 degreesC. The 10% mass-loss temperature was above 405degreesC under nitrogen. Structures of monomers 2-4 and the polymers were confirmed by Fourier transform infrared spectroscopy, H-1 NMR, and mass spectrometry. Good solubility of these polymers in polar solvents such as N-methylpyrrolidone, dimethylformamide, dimethylacetamide (DMAc), and m-cresol was observed, and tough, flexible films were obtained from the polymer's DMAc solutions. The effect of the substituted group on the physical property of polymers was also investigated. (C) 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2026-2030,2004.