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Indexed by:期刊论文

Date of Publication:2011-09-01

Journal:SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY

Included Journals:Scopus、SCIE、EI、PubMed

Volume:79

Issue:5

Page Number:1896-1903

ISSN No.:1386-1425

Key Words:Diffuse bi-directional pulsed discharge; Nanosecond pulse; Dielectric barrier discharge; Optical emission spectra; Atmospheric pressure

Abstract:In this study, a bi-directional high voltage pulse with 20 ns rising time is employed to generate diffuse glow-like dielectric barrier discharge plasma with very low gas temperature in N(2) using needle-plate electrode configuration at atmospheric pressure. Both the diffuse nanosecond pulsed dielectric barrier discharge images and the optical emission spectra of the discharge are recorded successfully under severe electromagnetic interference. The effects of pulse peak voltage, pulse repetition rate, and the concentrations of Ar and O(2) on the emission intensities of NO (A(2)Sigma -> X(2)Pi), OH (A(2)Sigma -> X(2)Pi, 0-0), N(2) (C(3)Pi(u) -> B(3)Pi(g), 0-0, 337.1 nm), and N(2)(+) (B(2)Sigma(+)(u) -> X(2)Sigma(+)(g), 0-0, 391.4 nm) are investigated. The effects of the concentrations of Ar and O(2) on the discharge diffuse performance are also studied. It is found that the emission intensities of NO (A(2)Sigma -> X(2)Pi), OH (A(2)Sigma -> X(2)Pi, 0-0), N(2) (C(3)Pi(u) -> B(3)Pi(g), 0-0, 337.1 nm), and N(2)(+) (B(2)Sigma(+)(u) -> X(2)Sigma(+)(g), 0-0, 391.4 nm) rise with increasing pulse peak voltage, pulse repetition rate, and the concentration of Ar, but decrease with increasing the concentration of O(2). The main physicochemical processes involved are also discussed. (C) 2011 Elsevier B.V. All rights reserved.