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论文类型：期刊论文

第一作者：Zhang, Xiaodan

通讯作者：Li, YM; Duan, CY (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China.

合写作者：Li, Yaming,Hao, Xinyu,Jin, Kun,Zhang, Rong,Duan, Chunying

发表时间：2018-04-12

发表刊物：TETRAHEDRON

收录刊物：SCIE

卷号：74

期号：15

页面范围：1742-1748

ISSN号：0040-4020

关键字：Coumarin; Perfluoroalkylation; Visible light; Recoverable photocatalyst

摘要：A recyclable Ruthenium tris [4,4'-bis (dinonylmethyl)-2,2'-bipyridine] (Ru[(DNM)(2)bpy](3)(2+)) photocatalyst (PC) was synthesized. Hexane-phase-selective solubility allowed its simple and efficient separation from reaction products via solvent extraction. The excellent catalytic activity and recoverability were demonstrated in batch and flow perfluoroalkylation reactions of coumarin under visible-light irradiation. High reaction rates and easy reusability of the catalyst make this approach attractive for large-scale applications. (C) 2018 Elsevier Ltd. All rights reserved.