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论文类型：期刊论文

第一作者：Huang, Ping

通讯作者：Li, YM; Duan, CY (reprint author), Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116024, Liaoning, Peoples R China.

合写作者：Li, Yaming,Fu, Xinmei,Zhang, Rong,Jin, Kun,Wang, Wenxin,Duan, Chunying

发表时间：2016-10-19

发表刊物：TETRAHEDRON LETTERS

收录刊物：SCIE、Scopus

卷号：57

期号：42

页面范围：4705-4708

ISSN号：0040-4039

关键字：Trifluoromethylation; Denitrative coupling reaction; Stereoselectivity; Ag(I)-catalyzed

摘要：A novel and convenient approach to the synthesis of substituted beta-trifluoromethyl styrenes via a silver(I)-catalyzed denitrative trifluoromethylation with CF3SO2Na under relatively mild conditions has been developed. This protocol delivered excellent stereoselectivity and showed wide substrate tolerance. (C) 2016 Elsevier Ltd. All rights reserved.