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    靳焜

    • 高级工程师      
    • 性别:女
    • 毕业院校:抚顺石油学院
    • 学位:学士
    • 所在单位:化工学院
    • 电子邮箱:jinkun@dlut.edu.cn

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    Copper-mediated oxidative trifluoromethylthiolation of aryl boronic acids with CF3CO2Na and elemental sulfur

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    论文类型:期刊论文

    第一作者:Zhai, Lijuan

    通讯作者:Li, YM (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China.

    合写作者:Li, Yaming,Yin, Jun,Jin, Kun,Zhang, Rong,Fu, Xinmei,Duan, Chunying

    发表时间:2013-12-02

    发表刊物:TETRAHEDRON

    收录刊物:SCIE、Scopus

    卷号:69

    期号:48

    页面范围:10262-10266

    ISSN号:0040-4020

    关键字:Copper-mediated; Oxidation; Trifluoromethylthiolation; Sodium trifluoroacetate; Synthetic methods

    摘要:A practical three-component copper-mediated oxidative trifluoromethylthiolation of aryl boronic acids with cheap and readily available sodium trifluoroacetate and elemental sulfur is reported. A variety of trifluoromethylthio-substituted aromatics are synthesized in moderate yields under mild reaction conditions. (C) 2013 Elsevier Ltd. All rights reserved.