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论文类型：期刊论文

第一作者：Lu, Yang

通讯作者：Li, YM (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China.

合写作者：Li, Yaming,Zhang, Rong,Jin, Kun,Duan, Chunying

发表时间：2013-11-11

发表刊物：TETRAHEDRON

收录刊物：SCIE、Scopus

卷号：69

期号：45

页面范围：9422-9427

ISSN号：0040-4020

关键字：ortho-Nitration; Aromatic amines; Bismuth nitrate; Regioselectivity; Synthetic methods

摘要：An efficient and one-pot synthetic method for the regioselective ortho-nitration of the N-phenyl carboxamides and primary anilines has been developed by using bismuth nitrate and acetic anhydride as the nitrating reagents. Reaction proceeds at room temperature and results in corresponding ortho-nitrated products in moderate to excellent yields. This method provides an operationally simple, regioselective, and efficient access to synthesize o-nitro anilines under the mild conditions. (C) 2013 Elsevier Ltd. All rights reserved.