点击次数：

论文类型：期刊论文

第一作者：Li, Yaming

通讯作者：Li, YM (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, Sch Chem Engn, Dalian 116024, Peoples R China.

合写作者：Chen, Tao,Wang, Huifeng,Zhang, Rong,Jin, Kun,Wang, Xiuna,Duan, Chunying

发表时间：2011-07-01

发表刊物：SYNLETT

收录刊物：SCIE

期号：12

页面范围：1713-1716

ISSN号：0936-5214

关键字：copper-catalyzed; trifluoromethylation; decarboxylative; silver oxide; cross-coupling

摘要：A practical and ligand-free Cu-catalyzed decarboxylative trifluoromethylation of aryl iodides with sodium trifluoroacetate using Ag2O as a promoter was reported. A variety of trifluoromethyl-substituted aromatics are synthesized in moderate to excellent yields and with wide functional-group tolerance under relatively mild reaction conditions.