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Date of Publication:2022-10-10
Journal:高分子材料科学与工程
Volume:28
Issue:5
Page Number:20-23
ISSN No.:1000-7555
Abstract:1,3,5-Triazine-based polymers are well-known for their outstanding
comprehensive properties including excellent thermal stability,high
strength and modulus,good flame retardance and chemical
resistance.However,such polymers always exhibit high melt or infusion
temperatures together with poor solubility,and high-molecular-weight
polymers are frequently prepared at high temperature under high
pressure,which hamper their wide spread utilization as high-performance
separation membranes,insulting coatings or sealants.By using molecular
design,new series of soluble and heat-resistant poly(aryl ether)s
containing 1,3,5-triazine moieties were prepared by the incorporation of
flexible pendant groups,unsymmetrical units,kink or twisted non-coplanar
moieties into the polymer chain.The effect of molecular structure on
polymer solubility,thermal stability and mechanical strength was
investigated in this paper.
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