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内表面沉积的类金刚石薄膜的喇曼光谱表征

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Date of Publication:2009-01-01

Journal:核聚变与等离子体物理

Issue:1

Page Number:82-86

ISSN No.:0254-6086

Abstract:Diamond-like carbon (DLC) films deposition on inner surface of a stainless steel tube with 100mm in length and 10mm in inner diameter is carried out in direct current glow discharge plasma of Ar/CH 4 mixed gas with a flow ratio of 20% CH 4, and the influence of pressure and deposition time on micro-structure of the films is investigated by Raman spectroscopy. It is found that the position of both G and D line, the width (FWHM) of both G and D line and the I D/I G ratio all drop firstly and then rise along with the pressure increase, the lowest values occur when the pressure is 20Pa. On the other hand, along with the time evolution the position of both G and D line shift to the lower wave-number, the width (FWHM) and the I D/I G ratio of both G and D line decrease. These results reveal that the DLC films become harder, more ordered and more diamond-like with higher sp 3 content, and the size of sp 3 cluster grows larger along with the time evolution.

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