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Indexed by:期刊论文

Date of Publication:2017-07-15

Journal:CATALYSIS TODAY

Included Journals:SCIE、EI、Scopus

Volume:290

Page Number:73-77

ISSN No.:0920-5861

Key Words:Water oxidation; Electrochemistry; Molecular catalyst; Polymerization; alpha-Fe2O3

Abstract:Ru-bda based molecular water oxidation catalysts 1 and 2 (H(2)bda = 2,2'-bipyridine-6,6'-dicarboxylic acid) containing a thiophene group are attached to the surfaces of electrodes by the method of electropolymerization. The Ru-bda molecular catalyst functionalized graphite carbon electrode can catalyze water oxidation efficiently under a overpotential of ca 500 mV to obtain current density of 5 mA cm(-2); and the similarly functionalized photoelectrode based on alpha-Fe2O3 (hematite) film can work as an photoanode for light driven water splitting. (C) 2016 Elsevier B.V. All rights reserved.