Release Time:2019-03-12  Hits:

Indexed by: Journal Article

Date of Publication: 2017-04-21

Journal: CHEMICAL COMMUNICATIONS

Included Journals: PubMed、SCIE

Volume: 53

Issue: 31

Page Number: 4374-4377

ISSN: 1359-7345

Abstract: Two water soluble copper(II) complexes containing amine-pyridine ligands were found to be catalytically active for water oxidation reactions in basic solutions, with observed rate constants of 13.1-18.7 s(-1). These complexes are robust in basic solutions and displayed good stability over 5 h of electrolysis in pH 11.5 phosphate buffer at 1.4 V vs. NHE.