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Electrocatalytic water oxidation by copper(II) complexes containing a tetra- or pentadentate amine-pyridine ligand

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Indexed by:期刊论文

Date of Publication:2017-04-21

Journal:CHEMICAL COMMUNICATIONS

Included Journals:SCIE、PubMed

Volume:53

Issue:31

Page Number:4374-4377

ISSN No.:1359-7345

Abstract:Two water soluble copper(II) complexes containing amine-pyridine ligands were found to be catalytically active for water oxidation reactions in basic solutions, with observed rate constants of 13.1-18.7 s(-1). These complexes are robust in basic solutions and displayed good stability over 5 h of electrolysis in pH 11.5 phosphate buffer at 1.4 V vs. NHE.

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