Release Time:2019-03-13  Hits:

Indexed by: Journal Article

Date of Publication: 2010-12-14

Journal: CHEMICAL COMMUNICATIONS

Included Journals: Scopus、SCIE、PubMed

Volume: 46

Issue: 46

Page Number: 8806-8808

ISSN: 1359-7345

Abstract: Among three noble-metal-free molecular devices (1-3) containing a porphyrin photosensitizer and a cobaloxime catalyst, the one with a zinc porphyrin unit displayed apparently higher efficiency for photoinduced H-2 production than complex 2 with a magnesium porphyrin and 3 with a free-base porphyrin, possibly due to the formation of a TEA center dot center dot center dot ZnPor-Co triad in solution.