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Photochemical H-2 production with noble-metal-free molecular devices comprising a porphyrin photosensitizer and a cobaloxime catalyst

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Indexed by:期刊论文

Date of Publication:2010-12-14

Journal:CHEMICAL COMMUNICATIONS

Included Journals:PubMed、SCIE、Scopus

Volume:46

Issue:46

Page Number:8806-8808

ISSN No.:1359-7345

Abstract:Among three noble-metal-free molecular devices (1-3) containing a porphyrin photosensitizer and a cobaloxime catalyst, the one with a zinc porphyrin unit displayed apparently higher efficiency for photoinduced H-2 production than complex 2 with a magnesium porphyrin and 3 with a free-base porphyrin, possibly due to the formation of a TEA center dot center dot center dot ZnPor-Co triad in solution.

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