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Molecular engineering for efficient and selective iron porphyrin catalysts for electrochemical reduction of CO2 to CO

Release Time:2019-03-13  Hits:

Indexed by: Journal Article

Date of Publication: 2016-12-13

Journal: CHEMICAL COMMUNICATIONS

Included Journals: PubMed、SCIE

Volume: 52

Issue: 100

Page Number: 14478-14481

ISSN: 1359-7345

Abstract: Iron porphyrins Fe-pE, Fe-mE, and Fe-oE were synthesized and their electrochemical behavior for CO2 reduction to CO has been investigated. The controlled potential electrolysis of Fe-mE gave exclusive 65% Faradaic efficiency (FE) whereas Fe-oE achieved quasi-quantitative 98% FE (2% H-2) for CO production.

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