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Indexed by:期刊论文

Date of Publication:2016-01-01

Journal:JOURNAL OF MATERIALS CHEMISTRY A

Included Journals:SCIE、EI

Volume:4

Issue:38

Page Number:14550-14554

ISSN No.:2050-7488

Abstract:A new redox couple, [Cu(bpye)(2)](+/2+), has been synthesized, and applied in dye-sensitized solar cells (DSSCs). Overall efficiencies of 9.0% at 1 sun and 9.9% at 0.5 sun were obtained, which are considerably higher than those obtained for cells containing the reference redox couple, [Co(bpy)(3)](2+/3+). These results represent a record for copper-based complex redox systems in liquid DSSCs. Fast dye regeneration, sluggish recombination loss processes, faster electron self-exchange reactions and suitable redox potentials are the main reasons for the observed increase in efficiency. In particular, the main disadvantage of cobalt complex-based redox couples, charge-transport problems, appears to be resolved by a change to copper complex redox couples. The results make copper complex-based redox couples very promising for further development of highly efficient DSSCs.