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An iron-based thin film as a highly efficient catalyst for electrochemical water oxidation in a carbonate electrolyte

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Indexed by:Journal Papers

Date of Publication:2016-04-28

Journal:CHEMICAL COMMUNICATIONS

Included Journals:PubMed、SCIE

Volume:52

Issue:33

Page Number:5753-5756

ISSN No.:1359-7345

Abstract:A highly active iron-based water-oxidation catalyst was electro-deposited from a CO2 saturated bicarbonate solution containing Fe2+. This catalyst (Fe-Ci) produces a current density of 10 mA cm(-2) at an overpotential of 560 mV and the activity remains constant over 18 h in the environmentally benign HCO3-/CO32- buffer (pH 9.75). A Tafel slope of 34 mV dec(-1) was obtained for Fe-Ci, which is lower than other reported values for iron-based catalysts.

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