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High-efficiency dye-sensitized solar cells with molecular copper phenanthroline as solid hole conductor

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Indexed by:期刊论文

Date of Publication:2015-09-01

Journal:ENERGY & ENVIRONMENTAL SCIENCE

Included Journals:SCIE、EI、Scopus

Volume:8

Issue:9

Page Number:2634-2637

ISSN No.:1754-5692

Abstract:Copper phenanthroline complexes in the solid phase can act as efficient molecular hole transporting material (HTM) for hybrid solar cells. We prepared solid-state dye-sensitized solar cells with the organic dye LEG4 and bis(2,9-dimethyl-1,10-phenanthroline)copper(I/II) (Cu(dmp)(2)) and achieved power conversion efficiencies of more than 8% under 1000 W m(-2) AM1.5G illumination, with open-circuit potentials of more than 1.0 V. The successful application of a copper-complex based HTM paves the way for low-cost and efficient hybrid solar cells, as well as for other opto-electronic devices.

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