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Electrochemical driven water oxidation by molecular catalysts in situ polymerized on the surface of graphite carbon electrode

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Indexed by:期刊论文

Date of Publication:2015-01-01

Journal:CHEMICAL COMMUNICATIONS

Included Journals:SCIE、Scopus

Volume:51

Issue:37

Page Number:7883-7886

ISSN No.:1359-7345

Abstract:A simple strategy to immobilize highly efficient ruthenium based molecular water-oxidation catalysts on the basal-plane pyrolytic graphite electrode (BPG) by polymerization has been demonstrated. The electrode 1@BPG has obtained a high initial turnover frequency (TOF) of 10.47 s(-1) at similar to 700 mV overpotential, and a high turnover number (TON) up to 31600 in 1 h electrolysis.

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