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A nonheme manganese(IV)-oxo species generated in photocatalytic reaction using water as an oxygen source

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Indexed by:期刊论文

Date of Publication:2015-03-07

Journal:CHEMICAL COMMUNICATIONS

Included Journals:PubMed、SCIE、Scopus

Volume:51

Issue:19

Page Number:4013-4016

ISSN No.:1359-7345

Abstract:A nonheme manganese(IV)-oxo complex, [Mn-IV(O)(BQCN)](2+), was generated in the photochemical and chemical oxidation of [Mn-II(BQCN)](2+) with water as an oxygen source, respectively. The photocatalytic oxidation of organic substrates, such as alcohol and sulfide, by [Mn-II(BQCN)](2+) has been demonstrated in both neutral and acidic media.

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