Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2014-08-25

Journal: CHEMICAL COMMUNICATIONS

Included Journals: Scopus、SCIE、PubMed

Volume: 50

Issue: 66

Page Number: 9255-9258

ISSN: 1359-7345

Abstract: Two-electron oxidation of a diiron complex (1) containing a bulky S-to-S bridge with an exocyclic carbonyl group affords [1(OH)](+), which replicates the coordination structure and electronic configuration of H-ox(air), and the chemically reversible reaction between 1 and [1(OH)](+) mimics the bioprocess of interconversion of the inactive H-ox(air) and the active H-red states of the [FeFe]-hydrogenases.