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Indexed by:期刊论文

Date of Publication:2014-08-25

Journal:CHEMICAL COMMUNICATIONS

Included Journals:PubMed、SCIE、Scopus

Volume:50

Issue:66

Page Number:9255-9258

ISSN No.:1359-7345

Abstract:Two-electron oxidation of a diiron complex (1) containing a bulky S-to-S bridge with an exocyclic carbonyl group affords [1(OH)](+), which replicates the coordination structure and electronic configuration of H-ox(air), and the chemically reversible reaction between 1 and [1(OH)](+) mimics the bioprocess of interconversion of the inactive H-ox(air) and the active H-red states of the [FeFe]-hydrogenases.