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Two Redox Couples are Better Than One: Improved Current and Fill Factor from Cobalt-Based Electrolytes in Dye-Sensitized Solar Cells

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Indexed by:期刊论文

Date of Publication:2014-06-01

Journal:ADVANCED ENERGY MATERIALS

Included Journals:SCIE、EI、Scopus

Volume:4

Issue:8

ISSN No.:1614-6832

Abstract:A tandem redox strategy is used in cobalt-based electrolytes. Co(bpy) 32+/Co(bpy)33+ offers a high photovoltage at the photoanode, whereas the I-/I3 - or Fc/Fc+ redox couples facilitate charge transfer at the counter electrode. Electron exchange in the electrolyte offers beneficial concentration gradients. The overall conversion efficiency is improved from 6.5% to 7.5%. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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