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Indexed by:期刊论文

Date of Publication:2014-01-01

Journal:PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Included Journals:SCIE、Scopus

Volume:16

Issue:46

Page Number:25234-25240

ISSN No.:1463-9076

Abstract:Photoelectrochemical (PEC) cells using molecular catalysts to split water into hydrogen and oxygen have been investigated intensively during the past years. However, the high-cost of Pt counter electrodes and instability of molecular PEC cells hinder the practical applications. We describe in this article a Pt-free tandem molecular PEC cell, for the first time, employing molecular ruthenium- and cobalt-catalysts with strong dipicolinic acid anchoring groups on the respective photoanode and photocathode for total water splitting. The Pt-free tandem molecular PEC cell showed an effective and steady photocurrent density of ca. 25 mu A cm(-2) for water splitting driven by visible light without external bias. This study indicates that tandem molecular PEC cells can provide great potential to the Pt-free devices for light driven total water splitting.