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Electrocatalytic hydrogen evolution from neutral water by molecular cobalt tripyridine-diamine complexes

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Indexed by:期刊论文

Date of Publication:2013-10-21

Journal:CHEMICAL COMMUNICATIONS

Included Journals:SCIE、PubMed、Scopus

Volume:49

Issue:82

Page Number:9455-9457

ISSN No.:1359-7345

Abstract:A cobalt complex with a tripyridine-diamine pentadentate ligand was found to be a highly active catalyst for electrochemical H-2 production from neutral water, with an activity of 860 mol H-2 (mol cat)(-1) h(-1) (cm(2) Hg)(-1) over 60 h CPE experiment at-1.25 V in a pH 7 phosphate buffer solution, without considerable deactivation.

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