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Electrocatalytic hydrogen evolution from neutral water by molecular cobalt tripyridine-diamine complexes

Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2013-10-21

Journal: CHEMICAL COMMUNICATIONS

Included Journals: Scopus、PubMed、SCIE

Volume: 49

Issue: 82

Page Number: 9455-9457

ISSN: 1359-7345

Abstract: A cobalt complex with a tripyridine-diamine pentadentate ligand was found to be a highly active catalyst for electrochemical H-2 production from neutral water, with an activity of 860 mol H-2 (mol cat)(-1) h(-1) (cm(2) Hg)(-1) over 60 h CPE experiment at-1.25 V in a pH 7 phosphate buffer solution, without considerable deactivation.

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