Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2012-10-01

Journal: CHEMISTRY-A EUROPEAN JOURNAL

Included Journals: Scopus、EI、SCIE、PubMed

Volume: 18

Issue: 44

Page Number: 13968-13973

ISSN: 0947-6539

Key Words: electrochemistry; electron transfer; hydrogenase; iron complexes

Abstract: [FeFe] hydrogenase mimics: two polynuclear iron-sulfur complexes (1 and 2) were prepared and structurally characterized. They are potentially effective and stable multielectron-transfer relays for mediating four- and six-electron transformations via a cascade of reversible two-electron redox steps with relatively narrow potential spans.Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.