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Indexed by:期刊论文

Date of Publication:2012-10-01

Journal:CHEMISTRY-A EUROPEAN JOURNAL

Included Journals:PubMed、SCIE、EI、Scopus

Volume:18

Issue:44

Page Number:13968-13973

ISSN No.:0947-6539

Key Words:electrochemistry; electron transfer; hydrogenase; iron complexes

Abstract:[FeFe] hydrogenase mimics: two polynuclear iron-sulfur complexes (1 and 2) were prepared and structurally characterized. They are potentially effective and stable multielectron-transfer relays for mediating four- and six-electron transformations via a cascade of reversible two-electron redox steps with relatively narrow potential spans.Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.