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Indexed by:期刊论文

Date of Publication:2010-11-15

Journal:ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Included Journals:SCIE、EI、Scopus

Volume:49

Issue:47

Page Number:8934-8937

ISSN No.:1433-7851

Key Words:carboxylate ligands; homogeneous catalysis; photocatalysis; ruthenium; water splitting

Abstract:Here splits the sun: A dinuclear ruthenium complex has been synthesized and employed to catalyze the homogeneous water oxidation (see picture; purple Ru, green Cl, blue N, red O). An exceptionally high turnover number was observed both for chemical (CeIVas the oxidant) and light-driven ([Ru(bpy)3]2+-type photosensitizers) water splitting. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.