Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2010-11-15

Journal: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Included Journals: Scopus、EI、SCIE

Volume: 49

Issue: 47

Page Number: 8934-8937

ISSN: 1433-7851

Key Words: carboxylate ligands; homogeneous catalysis; photocatalysis; ruthenium; water splitting

Abstract: Here splits the sun: A dinuclear ruthenium complex has been synthesized and employed to catalyze the homogeneous water oxidation (see picture; purple Ru, green Cl, blue N, red O). An exceptionally high turnover number was observed both for chemical (CeIVas the oxidant) and light-driven ([Ru(bpy)3]2+-type photosensitizers) water splitting. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.