Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2009-07-01

Journal: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Included Journals: SCIE、EI

Volume: 131

Issue: 25

Page Number: 8726-+

ISSN: 0002-7863

Abstract: A manganese(III) corrole complex, 1, has been synthesized and used to study a potential mechanism for oxidation of water to molecular oxygen. Oxidation by t-BuOOH gave the Mn-V=O complex 2. Addition of hydroxide Led to release of oxygen via the Mn-IV complex 4 and regeneration of complex 1. It could be shown that the oxygen from O-18-labeted water was incorporated in both the formed molecular oxygen and the peroxy intermediate 4.