Release Time:2019-03-10  Hits:

Indexed by: Journal Article

Date of Publication: 2008-11-30

Journal: CHEMICAL COMMUNICATIONS

Included Journals: Scopus、PubMed、SCIE

Issue: 44

Page Number: 5800-5802

ISSN: 1359-7345

Abstract: A diiron dithiolate complex holding a mu-hydride on the iron atoms and a proton on the basic site of a chelating diphosphine ligand was prepared and crystallographically characterized as a structural model of the [FeFe]-hydrogenase active site, and its molecular structure shows the H(mu)(-)center dot center dot center dot H(N)(+) distance is 3.934 angstrom.