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A proton-hydride diiron complex with a base-containing diphosphine ligand relevant to the [FeFe]-hydrogenase active site

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Indexed by:期刊论文

Date of Publication:2008-11-30

Journal:CHEMICAL COMMUNICATIONS

Included Journals:SCIE、PubMed、Scopus

Issue:44

Page Number:5800-5802

ISSN No.:1359-7345

Abstract:A diiron dithiolate complex holding a mu-hydride on the iron atoms and a proton on the basic site of a chelating diphosphine ligand was prepared and crystallographically characterized as a structural model of the [FeFe]-hydrogenase active site, and its molecular structure shows the H(mu)(-)center dot center dot center dot H(N)(+) distance is 3.934 angstrom.

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