Release Time:2019-03-10  Hits:

Indexed by: Journal Article

Date of Publication: 2008-01-01

Journal: CRYSTENGCOMM

Included Journals: SCIE

Volume: 10

Issue: 3

Page Number: 267-269

ISSN: 1466-8033

Abstract: A diiron complex [{(mu-SCH2)(2)CH2}{Fe-2(CO)(5)P(CH2OH)(3)}] was prepared as a biomimic of the [2Fe2S] subunit in the active site of [FeFe] hydrogenases, which appears as a supramolecular self-assembly in the solid state with O-H center dot center dot center dot O hydrogen bonds forming two-dimensional arrays with alternately right- and left-handed helical O-H center dot center dot center dot O-H chains.