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Indexed by:期刊论文

Date of Publication:2008-01-01

Journal:CRYSTENGCOMM

Included Journals:SCIE

Volume:10

Issue:3

Page Number:267-269

ISSN No.:1466-8033

Abstract:A diiron complex [{(mu-SCH2)(2)CH2}{Fe-2(CO)(5)P(CH2OH)(3)}] was prepared as a biomimic of the [2Fe2S] subunit in the active site of [FeFe] hydrogenases, which appears as a supramolecular self-assembly in the solid state with O-H center dot center dot center dot O hydrogen bonds forming two-dimensional arrays with alternately right- and left-handed helical O-H center dot center dot center dot O-H chains.