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Indexed by:期刊论文
Date of Publication:2007-09-01
Journal:EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Included Journals:SCIE、Scopus
Issue:26
Page Number:4128-4131
ISSN No.:1434-1948
Key Words:benzimidazolyl ligand; redox switch; reversible protonation and deprotonation; Ru-II complex
Abstract:A monoruthenium(II) complex of the benzimidazolyl ligand and its deprotonated counterpart were prepared and structurally characterized. The reversible protonation/deprotonation process of the ancillary ligand switches the redox potential of the ruthenium(II) core from 0.69 to 0.26 V vs. Ag/AgNO3. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)