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Indexed by:会议论文
Date of Publication:2007-10-01
Key Words:金属配合物;分子内协同催化;环氧烷烃;不对称环加成反应
Abstract:不对称催化合成是现代有机化学中最为活跃的研究领域之一。产物的构筑。本文论述了基于手性Salen型钻配合物的含手性亲电试剂和亲核试剂的双组分催化剂，成功实现了在室温、低压的温和条件下用外消旋环氧烷烃为原料直接一步合成光学活性环状碳酸酯。
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