Release Time:2019-03-10  Hits:

Indexed by: Journal Article

Date of Publication: 2007-01-01

Journal: JOURNAL OF PORPHYRINS AND PHTHALOCYANINES

Included Journals: Scopus、SCIE

Volume: 11

Issue: 5-6

Page Number: 463-469

ISSN: 1088-4246

Key Words: Cu(III) corrole; [Ru(bpy)(3)](2+); OEC; photosystem II; water oxidation

Abstract: A novel binuclear Ru-Cu complex, composed of a copper(III)-corrole and a ruthenium(II) tris(bipyridine) moicty linked by an amide bond, has been synthesized and characterized by H-1 NMR, UV-vis and mass spectrometry. The steady-state emission and the electrochemical properties were investigated. Compared to the parent [Ru(bpy)(3)](2+), the emission-of the desired complex was substantially quenched when the MLCT of [Ru(bpy)(3)](2+) was selectively photoexcited. Copyright (C) 2007. Society of Porphyrins & Phthalocyanines.