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An insight into the protonation property of a diiron azadithiolate complex pertinent to the active site of Fe-only hydirogenases

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Indexed by:Journal Papers

Date of Publication:2006-01-21

Journal:CHEMICAL COMMUNICATIONS

Included Journals:SCIE、PubMed

Issue:3

Page Number:305-307

ISSN No.:1359-7345

Abstract:Protonation of [{(mu-SCH2)(2)N(C6H4-p-NO2)}{Fe(CO)(2)(PMe3)}(2)] in the presence of 4 equiv. of HOTf afforded two species, a mu-hydride diiron complex, the molecular structure of which was crystallographically characterized, and a p-S-protonated species, which was readily deprotonated in the presence of pyridine.

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