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Synthesis and property of a chiral salen Mn(III) complex covalently linked to an Ru(II) tris(bipyridyl) photosensitizer

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Indexed by:期刊论文

Date of Publication:2005-07-01

Journal:INORGANIC CHEMISTRY COMMUNICATIONS

Included Journals:SCIE、Scopus

Volume:8

Issue:7

Page Number:606-609

ISSN No.:1387-7003

Key Words:manganese complex; ruthenium complex; heterobinuclear complex; chiral salen ligand; pyrrolidine; light-driven catalyst

Abstract:A catalyst-photo sensitizer binuclear Mn(III)Ru(II) complex was prepared, in which the catalyst moiety of the Mn(III) unit with a chiral pyrrolidine salen ligand was covalently linked to a photosensitizer of the Ru(II) tris(bipyridyl) fragment. The electrochemical and photophysical properties of the Mn(III)Ru(II) complex were studied. (c) 2005 Elsevier B.V. All rights reserved.

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