Synthesis and property of a chiral salen Mn(III) complex covalently linked to an Ru(II) tris(bipyridyl) photosensitizer
Release Time:2019-03-10 Hits:
Indexed by: Journal Article
Date of Publication: 2005-07-01
Journal: INORGANIC CHEMISTRY COMMUNICATIONS
Included Journals: Scopus、SCIE
Volume: 8
Issue: 7
Page Number: 606-609
ISSN: 1387-7003
Key Words: manganese complex; ruthenium complex; heterobinuclear complex; chiral salen ligand; pyrrolidine; light-driven catalyst
Abstract: A catalyst-photo sensitizer binuclear Mn(III)Ru(II) complex was prepared, in which the catalyst moiety of the Mn(III) unit with a chiral pyrrolidine salen ligand was covalently linked to a photosensitizer of the Ru(II) tris(bipyridyl) fragment. The electrochemical and photophysical properties of the Mn(III)Ru(II) complex were studied. (c) 2005 Elsevier B.V. All rights reserved.
Prev One:Spectroscopic and crystallographic evidence for the N-protonated (FeFeI)-Fe-I azadithiolate complex related to the active site of Fe-only hydrogenases
Next One:Influence of tertiary phosphanes on the coordination configurations and electrochemical properties of iron hydrogenase model complexes: Crystal structures of [(mu-S2C3H6)Fe-2(CO)(6-n)L-n] (L = PMe2Ph, n=1, 2; PPh3 P(OEt)(3), n=1)