Release Time:2019-03-10  Hits:

Indexed by: Journal Article

Date of Publication: 2005-01-01

Journal: CHINESE CHEMICAL LETTERS

Included Journals: ISTIC、SCIE、Scopus

Volume: 16

Issue: 1

Page Number: 89-92

ISSN: 1001-8417

Key Words: dinuclear complex; OEC; artificial photosynthesis

Abstract: Two novel high valent complexes [M-2(III, III)L(mu-OAc)(2)](PF6)-P-. (M=Mn, Fe; 9) were prepared, where L was the tri-anion of 2,6-bis{[(2-hydroxy-3-(morpholin-4-yl methyl)-5-tertbutyl benzyl)(pyridyl-2-methyl)amino]methyl}-4-methyl phenol which contained additional phenolic, tert-butyl and morpholin-4-yl methyl groups compared to its parent [Mn-2(II, II)(bpmp) (mu-OAc)(2)](CIO4)-C-. (10). These improvements decreased the difference between the new model and (Mn)(4) cluster (OEC in nature).