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Synthesis and photochemical properties of a new substituted phenol covalently linked to ruthenium (II) tris-bipyridine containing four ester groups as sensitizer

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Indexed by:期刊论文

Date of Publication:2004-12-01

Journal:CHINESE CHEMICAL LETTERS

Included Journals:Scopus、SCIE、ISTIC

Volume:15

Issue:12

Page Number:1407-1410

ISSN No.:1001-8417

Key Words:photosensitizer; ruthenium complex; phenolate ligand; nanocryatalline TiO2; solar cell

Abstract:As photosensitizer for solar cell, a new ruthenium (II) complex with four ester groups had been synthesized, in which a phenol substituted by {[(2-hydroxy-5-tert-butylbenzyl)(pyridyl-2-methyl)amino]methyl} is covalently linked to ruthenium (II) tris-bipyridine. The structures of the new compounds were confirmed by NMR and ESI-MS spectra. The electrochemical and photochemical properties were also studied.

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