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A solution-processable copper(II) phthalocyanine derivative as a dopant-free hole-transporting material for efficient and stable carbon counter electrode-based perovskite solar cells

Release Time:2019-03-11  Hits:

Indexed by: Journal Article

Date of Publication: 2017-09-14

Journal: JOURNAL OF MATERIALS CHEMISTRY A

Included Journals: EI、SCIE

Volume: 5

Issue: 34

Page Number: 17862-17866

ISSN: 2050-7488

Abstract: A solution-processable copper(II) phthalocyanine derivative coded as CuPc-TIPS has been synthesized and adopted as a hole-transporting material (HTM) in perovskite solar cells (PSCs), in combination with a mixed-ion perovskite absorber and a low-cost carbon cathode. Optimised PSC devices based on pristine CuPc-TIPS without any additives or dopants show a decent power conversion efficiency of 14.0% (measured at 100 mW cm(-2) illumination, AM 1.5G), together with a good long-termstability under ambient conditions. The present finding highlights the potential of solution-processed copper phthalocyanine derivative-based HTMs for the development of efficient and stable PSCs in the future.

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