![]() |
个人信息Personal Information
教授
博士生导师
硕士生导师
性别:男
毕业院校:大连理工大学
学位:博士
所在单位:化工学院
办公地点:大连理工大学西部校区E座421室
联系方式:手机:13998430917
电子邮箱:jubenzhi@dlut.edu.cn
Foaming Behavior of Dialdehyde Starch Schiff-base Derivatives
点击次数:
论文类型:期刊论文
发表时间:2013-07-01
发表刊物:TENSIDE SURFACTANTS DETERGENTS
收录刊物:SCIE、EI、Scopus
卷号:50
期号:4
页面范围:270-276
ISSN号:0932-3414
关键字:Dialdehyde starch-aniline Schiff-base; foaming behavior; surface activity
摘要:A foamable dialdehyde starch-aniline Schiff-base (DAS-AN) was synthesized by the reaction of dialdehyde starch (DAS) and oil-soluble aniline in a homogeneous dimethyl sulfoxide system under N-2 atmosphere. The DAS-ANs were characterized by gel permeation chromatography (GPC), Fourier-transform infrared spectroscopy (FT-IR) and NMR spectroscopy. Their foaming behavior and surface tension were investigated. Foaming power and stability tests were performed for solutions of DAS-ANs with different degrees of substitutions with aniline (DSAN) and concentrations. The maximum foaming power was 2.6 times the initial solution volume of the foam test in 450 mg . L-1 CaCO3 aqueous solution. The most stable foams only decreased by 6% in volume in deionized water after 20 min.