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论文类型：期刊论文

发表时间：2020-04-25

发表刊物：APPLIED CATALYSIS A-GENERAL

收录刊物：SCIE

卷号：596

ISSN号：0926-860X

关键字：Alkali metal doping; HCHO oxidation; CoMn oxide

摘要：Although CoMn oxides have shown promising catalytic properties in HCHO oxidation, their activities have a large space to improve especially at low temperatures ( < 70 degrees C). In the present study, Na or K doping into CoMn oxides was found to greatly enhance the low temperature activities, being one of the most active catalysts among non-noble metal catalysts. Na or K doping into CoMn oxides generates additional surface adsorbed oxygen and the amount of which has a linear relationship with the HCHO oxidation rate at 30 degrees C and 40 degrees C, which gives clear evidence of the crucial roles of surface adsorbed oxygen in HCHO oxidation. What is more, the positive effect of K doping was boosted when H2O was co-existed in the feed gas. The surface hydroxyl species generated from H2O dissociation directly participate in the HCHO oxidation, which provides a low activation energy pathway and increase the low temperature activity.